E.V. Zybina, D.V. Tashkinova, V.P. Smagin
Complex Formation of Europium (III) in Solutions Based on Carbon Tetrachloride and Trichloromethane
The effect of organic solvents based on carbon tetrachloride and trichloromethane, the type of anion and temperature on the interaction of europium (III) with 2,2`-dipyridyl (2,2`-Dipy) is studied by spectrophotometric methods. Features of electronic spectra of compounds are detected, the ratio of Eu (III): 2,2`-Dipy and stability constants of complex compounds are identified, changes in Gibbs energy, enthalpy and entropy in the process of the formation of complexes are calculated.
Key words: non-polar organic solvents, binary solvent, lanthanide compounds, complex formation, stability constants.