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The News of Altai State University
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3-1(71)2011
Chemistry

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E.V. Kondratova, A.V. Timiryazev, B.P. Shipunov, I.E. Stas

Offset Balance of the Chemical Reaction due to the Frequency and Time of Exposure to High-frequency Field

The impact of the low-power high-frequency electromagnetic field has been studied in relation to the equilibrium shift of the hydrolysis reaction for acetoacetic ester. It has been found out that the volume for the change in the equilibrium constant depends both on the applied frequency and on the time of exposure. The effect develops following the exposure of 5-15 days. For the frequencies under study the time dependence is of specific nature.
Key words: high-frequency electromagnetic field, equilibrium constant, shift in homogenous equilibrium, non-thermal impact.

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