B.I. Petrov, S.V. Shuliak
Education Adduct From Complex and Simple Salt Diantipyrylmethane at Extraction Cadmium (II) From Iodide Solutions
The ternary systems (AH)2[CdI4]#(AH)I # chloroform (I), dichloretan(II) or nitrobenzol (III) are investigated. A # diantipyrylmethane (IV). In I environment it is formed adduct (AH)2[CdI4](AH)I.
Character of change will carry out an electricity, viscosity izomaliarian solutions confirms structure adduct. The method of solubility finds a constant of reaction (AH)2[CdI4]+(AH)I = (AH)2[CdI4] (AH)I, Kср. = 0,61. The structure adduct is impossible to express the formula (AH)3[CdI5] Cadmium well extractions from iodide solutions in conditions of surplus in (AH)I I, hence, may not be part 3+anions, not capable to extraction IV. Connection (AH)2[CdI4] is bad let#s dissolve in IV and water solutions, therefore is allocated in a deposit at extractions macroquantity Сd2+ # if in I there is no surplus IV. In the environment II and III adducts is absent, solubility (AH)2<.sub>[CdI4] considerably grows and Сd2+ is taken practically stechiometrical by quantity IV.