The efficiency of effect of a high frequency field on parameters of Pb analytical signal in a method of stripping voltammetric on carbon and glassy carbon electrodes was studied. The obtained data were compared with a mercury film electrode data. The dependence of Pb anodic peak current on frequency of a HF-field on mercury film, carbon and glassy carbon electrodes were obtained. The polyextreme nature of dependence was showed. It was established, that frequencies of the maximum signal increase, and also degree of its increase depends of electrode's nature.